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Volume 15, Issue 1  (2006)

Editorial:
B.V. Toshev. "Khimiya" at 15

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Become a Friend: Friends of Khimiya (2006)

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News:
D. Klissurski. The One and Only: Professor Balarew (1885-1964) 7

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New Approaches:
F.L. Lambert. A Modern View of Entropy

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Teaching Efficiency:
P.R. Galcheva, K.V. Vachkov. Environment and Sustainable Development Learning Through Interactive Forms: Pupils' Self-Dependent Work 22
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Teaching Chemical Experiment:
A. Gendjova. On the Selection of Home Chemical Experiments for Enhancing 7th Grade Pupils' Interest to Chemistry 29
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History and Philosophy of Chemistry:
S. Moulay. Serendipity, The Hidden Parameter 40
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Reviews:
V. Simeonov. To Discover the Form (Ch. Daiev. Speciation Analysis, 2004, 122 pp.) 72
V. Yomtova. Protecting Groups (P.J. Kocienski. Protecting Groups, 2005, 668 pp.)

Full text: PDF (141 KB)

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Guide for Authors: 76
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Khimiya, Volume 15, Issue 1 (2006)

 Khimiya. 15, 13-21 (2006): 

Abstract. Entropy may be the most feared topic in beginning university chemistry - by students because of its complexity, by instrucors because students fail to understand its basic principles. Although in advanced areas entropy change can indeed be extremely complex and subtle, this is not the case in the first course. Historically, experts in thermodynamics have not aided beginners by providing an introduction to the subject in simple terms. Entropy is not 'disorder' nor does it have anything to do with 'mixed-up-things' like disorderly desks or shifted cards. This article in simple, step-wise fashion details how instructors can begin with ordinary physical and chemical events whose spontaneity can be seen to be due to energy dispersing or spreading out. Then this can be generalized to "energy of all types changes from being localized to becoming dispersed if it is not hindered from doing so. The overall process is an increase in thermodynamic entropy". Thus, the focus is on seeing the dispersial of molecular motional energy that instructors can readily apply to all the common examples of beginnig chemistry - including new insight to the meaning of S<298> and a quick introduction in mixing (usually omitted in the first course) that explains all colligative effects.

References:12

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 Khimiya. 15, 22-28 (2006): 

Abstract.  An object of the present elaboration is the application of pupils' self-dependent work in the course of learning chemistry as a way of putting into practice their environmental education in the light of the problem of sustainable development. It is a problem of the first significance since the society seeks the effective ways of building up personalities who are able to solve difficult tasks set in the social practice. The interactive methods of learning seem to be appropriate for achieving such objectives. One of these forms is pupils' self-dependent work. A proper classification of pupils' self-dependent work is presented and any item of it is illustrated by suitable examples. All this supports the thesis that the school subject 'Chemistry and Envirironment' would contribute to the implementation of the environmental studies for sustainable development as a new promosing field of the school practice.

References: 5

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 Khimiya. 15, 29-39 (2006): 

Abstract.  The paper deals with the criteria for proper selecting the contents of home chemical experiments designed to enhance the interest of the pupils to chemistry in the early chemistry education (7th grade). The criteria proposed are as follow: correspondence with the educational aims; interrelation and succession; integrality; novelty; originality; fun and entertainment; self-reliance stimulation. Each criterion is presented with a short discussion and illustrated with appropriate examples.

References: 15

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 Khimiya. 15, 40-71 (2006):

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Abstract. "Mission-oriented" and "curiosity-driven" researches sometimes lead to some spectucularly unexpected discoveries. Among the discoveries in chemistry and chemistry-related fields, the accidental ones remain undoubtedly the landmarks for the development of these disciplines and their overall related technology. Adventitious and inadvertent facets of the findings of some chemical substances as well as their applications make these discoveries a real wonder. The role of serendipity manifests in various ways making the research work blossom out. Mentioning the discoverers along with the different expressions of their immeasurable emotions right upon the findings will make this narration a special issue. The admiring words of some eminent chemists about the accidental discoveries beautify further this narration.

References: 32

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Khimiya. 15, 74-75 (2006):

[O]n the whole P. Kocienski's "Protecting Groups" is not only a thourough description of the tactics and art needed in using protecting groups, but also a work that demonstrates the scope and beauty of contemporary organic synthesis (Yomtova, 2006)

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