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Volume 15, Issue 5  (2006)

Curriculum Matters:
L.P. Antonova. On the Rationalization of Chemical Symbols and Chemical Formulas in the 7th Grade 331
Problems:
G. Pekov, P. Tsanova. XXXVII International Chemistry Olympiad: Problems with Solutions 339
Advanced Chemistry:
M. Mahdi Najafpour. Relativity in Chemistry 360
From the Research Laboratories:
G. Kumar, E.M.R. Kiremire, M.N. Srivastava. Synthesis and Characterization of Mixed Ligand Cobalt (II) Complexes of Nitrilotriacetic and Hippuric Acid 378
History and Philosophy of Chemistry:
B.V. Toshev. Chemical Literature from the Period of the Third Bulgarian Kingdom. 7. Dissertations

Full text: PDF (531 KB)

385
Reviews:
S. Manev. An Expected Issue (Trilingual Encyclopedia Nature) 394
Archives:
J. Kavalova, P. Lesseva, I. Diakova, E. Gelovska, A. Hineva. Assessing the knowledge and skills of 6-10-graders According to State Requirements for Educational Content     396
     

Khimiya, Volume 15, Issue 5 (2006)

Khimiya, 15, 331-338 (2006) 

Abstract. New textbooks for early chemistry learning have been recently introduced. One of them is the textbook by Bliznakov et al [2]. Its careful reading shows some disadvantages especially when discussing the topics of chemical symbols and chemical formulas. Recommendations for improving the text of that, generally successful, manual, are presented.

Keywords: chemical symbol; chemical formula; empiric formula; molecular formula

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Khimiya, 15, 339-359 (2006)

Abstract. The paper lists the problems of the XXXVII International Chemistry Olympiad (16-25 July 2005). The solutions of those problems are given.

Keywords: International Chemistry Olympiad; problems with solutions

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Khimiya, 15, 360-377 (2006)

 Abstract. Einstein's Special Theory of Relativity describes the motion of particles moving at close to the speed of light. In fact, it gives the correct laws of motion for any particle. This does not mean Newton was wrong; his equations are contained within the relativistic equations. Newton's "laws" provide a very good approximate form, valid when speed is much less than the speed of light. For particles moving at slow speeds (very much less than the speed of light), the differences between Einstein's laws of motion and those derived by Newton are tiny. That's why relativity doesn't play a large role in everyday life. The paper shows relativity is important in chemistry and should remember it when we say about heavy element.

Keywords: Heavy Elements, Relativistic Effects, Relativity in Chemistry

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Khimiya, 15. 378-384 (2006)

Abstract. Mixed ligand cobalt (II) complexes, ( Na2   [{N(CH2COO)3} (C6H5 CO NH CH2 COO)Co]. 6H2O) and (Na2[{N(CH2COO)3}(C6H5 CO NH CH2 COO)Co]) formed with nitrilotriacetic acid  and hippuric acid have been synthesized and characterized for the first time by their elemental analysis , magneto chemical measurements and spectral studies ( IR and electronic spectra). Nitrilotriacetic acid and hippuric acid show tetradentate and bidentate behavior respectively. With nitrilotriacetic acid, the coordination occurs through three carboxylic oxygen atoms  and  the nitrogen  atom, whereas hippuric acid coordinates through the oxygen atom of  the  carboxylic group and the nitrogen atom of the amido group. Cobalt (II) complexes have been suggested to show six fold octahedral structure (figure3).

   

       Keywords: synthesis, octahedral Co(II) complexes, nitrilotriacetic acid, hippuric acid, characterization

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Khimiya, 15, 385-393 (2006)

 Abstract. This is the last part of the complete bibliography of chemistry books published in the period of the Third Bulgarian Kingdom (1978-1946). Twenty one dissertations for the doctor degree of the University of Sofia are presented. The procedure of defending a thesis in this period is described. A concise history of the introduction of the PhD-system in the world universities is given. The comparison seems to be favorable for the system developed in the University of Sofia at that time. After all 511 chemistry books had been published in the Kingdom of Bulgaria. The following areas ate presented: school textbooks – 81 books (Khimiya, 8, 307-316 (1999)); chemical didactic textbooks and manuals – 44 books (Khimiya, 8, 317-322 (1999); university textbooks – 47 books (Khimiya, 10, 424-438 (2001)); technical and applied chemistry – 146 books (Khimiya, 12, 401—413 (2003)); chemistry for the daily life – 116 books (Khimiya, 13, 397-408 (2004)) and chemistry and warfare – 56 books (Khimiya, 13, 465-474 (2004)).

Keywords: Kingdom of Bulgaria; chemistry books; dissertations

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